Wednesday, October 31, 2012

Shaken, not Stirred

Given the free access from Springer until the end of November for Rheologica Acta [*], I've been scanning some of the journals to see if there are any interesting articles. One article caught my eye in particular, but I was disappointed after reading the article. First, the research and the results:

The authors dissolved various molecular weights of polyethylene oxide (PEO) in water, either by shaking the containers or by stirring them, in both cases over a period of 4 days. Surprise, surprise, the shaken samples had a higher viscosity than the stirred ones due to the mechanical breakdown in molecular weight of the more aggressive process. This only happened with higher molecular weight materials with 35,000 g/mole being the cut off.

As I said, I was pretty disappointed with the article. This is one of those cases where the results were pretty much expected even if they had never been published. Much like those data on the nonlinear rheology of polystyrene that I posted here a couple of weeks ago. It might not be a completely worthless effort to publish them somewhere but a 12-page article is overkill.

But it is pretty apparent that the referees never looked at the article. Consider this blooper on page 1 of the article:
"The specific chemical structure of PEO, HO − [(CH2)n − O]x −H with n = 2, confers to this polymer very unusual interactions with water. Indeed, while poly(methylene oxide) with n = 1 and poly(butylenes oxide) with n = 3 are both hydrophobic and insoluble in water..."
Psst! For n = 3, these would be poly(PROPYL-ene oxides). Oh brother...Thankfully, the quality of the other articles that I am reading is higher.

[*] You are taking advantage of this access, right? It also includes Colloid and Polymer Science,Polymer Bulletin, and Polymer Science Series A


Anonymous said...

I do trust all the ideas you have introduced in your post. They are really convincing and can definitely work. Nonetheless, the posts are too short for newbies. Could you please lengthen them a bit from next time? Thank you for the post.

Elina Rose said...

Different paints come with different properties, as they are manufactured for different purposes. Exterior paint is formulated to handle mildew and fading. Interior paint, on the other hand, is made to allow cleaning and resist staining. To understand the difference between these two types of paint, one needs to gain knowledge of the chemistry behind each type. Let’s take a closer look at both types and see how exactly they differ from one another website.